By Mitsugi Senda

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Extra info for Analytical Chemistry–4. International Union of Pure and Applied Chemistry

Example text

This impressive term was originally coined for the field of telecommunication where the "blank scatter", the atmospherics in a radio receiver or the thermal fluctua­ tions in the entrance resistor of an amplifier, can be made audible as 'noise' in a loudspeaker. The use of the term "(analytical) noise" in chemical analysis should not mislead one into supposing, by analogy, that the main source of fluctuations is to be found in the electronic part of the apparatus. Other sources of fluctuations often affect the blank measure (and the signal) more seriously; the electronic 'noise', even if perceptible, may be of no importance.

J. R. Majer and R. Perry, Chem. , 211 (1969). J. R. Majer and R. Perry, Chem. , 454 (1969). J. R. Majer, M. J. A. Reade and W. I. Stephen, Talanta, 15, 373 (1968). R. Belcher, J. R. Majer, R. Perry and W. I. Stephen, Anal. Chim. Acta, 45, 305 (1969). R. Belcher, J. R. Majer, R. Perry and W. I. Stephen, Anal. Chim. Acta, 43, 451 (1968). M. G. Allcock, R. Belcher, J. R. Majer and R. Perry, Anal. , 42, 776 (1970). J. R. Majer and M. J. A. Reade, Chem. , 58 (1970). 27 SUR L'ANALYSE DES REACTIONS EN MILIEU NON-AQUEUX AU MOYEN DES METHODES ELECTROCHIMIQUES G.

Elimination of the blank portion is necessary because the bottom of the basin may be uneven. This can be controlled by measuring the depth of the water. This odd story illustrates exactly the situation of the analyst involved in trace determinations. It may be helpful to convince salesmen, technicians, judges and other laymen in chemistry who demand reliable analytical results for traces, how difficult the work is and how carefully the results must be interpreted. 7. CALIBRATION METHODS FOR TRACE DETERMINATION During any analysis the sample under investigation is compared with the t R.

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